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The rearrangement of di-t-butylphenyl carbinol

โœ Scribed by P.D. Bartlett; T.R. Steadman; T.T. Tidwell; W.P. Weber

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
162 KB
Volume
11
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

There have been reports of the syntheses of the ortho and para methoxy derivatives of di-t_butylphenyl carbinollV2 and more recently there has been a report of the preparation of the parent compound 13. We report herein the preparation and characterization of i, its rearrangement to the isomeric secondary carbinol, and the implications of the multiplicity of its hydroxyl stretching frequency for conformational isanerism in the compound.

Di-&-butylphenyl carbinol (4) bp. 140-143" (12 am), was originally prepared some time ago4

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