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Preparation and reaction of sterically crowded N-(2,4-di-t-butylphenyl)-N-methylaminodichlorophosphine

✍ Scribed by François Rivière; Shigekazu Ito; Masaaki Yoshifuji

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
102 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

One of the o-t-butyl groups was eliminated from 2,4,6-tri-t-butyl-N-methylaniline by reaction with phosphorus trichloride in DME to afford sterically crowded N-(2,4-di-t-butylphenyl)-N-methylaminodichlorophosphine, which was utilized for preparation of a novel unsymmetrical diphosphene.

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