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The rearrangement of a tetrahydrobiphenylene derivative to a bridged benzocycloheptene

✍ Scribed by Barton, John W.; Howard, Judith A. K.; Shepherd, Michael K.; Stringer, Andrew M.

Book ID
121355456
Publisher
Royal Society of Chemistry
Year
1987
Weight
395 KB
Category
Article
ISSN
1472-7781

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## Abstract magnified image Free‐radical generated at C‐7 position of indole derivative bearing N‐(3′‐chloroallyl) group prompted a regioselective intramolecular cyclization to furnish pyrroloindoline derivative, through the more favorable __5‐exo‐trig__ cyclization mode. The pyrroloindoline compo