Rearrangement of a trishomocubane derivative to a tetracyclo[6.3.0.02,6.03,10]undec-4-ene
β Scribed by Alexander M. Aleksandrov; Mariusz Krawiec; Tonis J. Pehk; Alexander Petrenko; William H. Watson
- Book ID
- 105522418
- Publisher
- Springer
- Year
- 1996
- Tongue
- English
- Weight
- 290 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1040-0400
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π SIMILAR VOLUMES
## Abstract ^19^F and ^1^H NMR data are reported for fluoroβsubstituted tetracyclo[6.3.0.0^2,4^.0^3,7^]undecβ5βenes, which are products of the __meta__ photocycloaddition reaction of fluorobenzenes to cyclopentene. Heteroβ and homoβnuclear decoupling techniques were used to identify the adducts.
## Abstract Cyclooctatetraene is a common product of photolysis of the title compound la. Depending on reaction conditions it is accompanied by benzene (solvent: cyclohexane, Ξ³ = 253.7 nm), benzene plus semibullvalene (acetone, 300 nm), and an oxetane (cyclohexane, 350 nm, presence of an equimolar