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The reactivity of triplet carbenes: An ab initio study

✍ Scribed by Miquel Moreno; José M. Lluch; Antonio Oliva; Juan Bertrán


Book ID
118208777
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
584 KB
Volume
164
Category
Article
ISSN
0166-1280

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ab initio calculations were carried out for three exocyclic allcylidene carbenes. Cyclopentadienylvinyl carbene is predicted to be highly electrophilic while the cyclopropenylidenevinyl carbene may provide the first example of a nucleophilic alkylidene carbene. Unsaturated carbenes 1, where the div