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An ab Initio Investigation of Fluorobromo Carbene

✍ Scribed by Sun, Erping; Li, Rui; Sun, Qixiang; Wei, Changli; Xu, Haifeng; Yan, Bing

Book ID
120294993
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
290 KB
Volume
116
Category
Article
ISSN
1089-5639

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ab initio calculations were carried out for three exocyclic allcylidene carbenes. Cyclopentadienylvinyl carbene is predicted to be highly electrophilic while the cyclopropenylidenevinyl carbene may provide the first example of a nucleophilic alkylidene carbene. Unsaturated carbenes 1, where the div