The reactivity of polystyryl radicals towards various alkyl substituted styrenes
β Scribed by P. W. Kwant
- Book ID
- 104703592
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 152 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
Abstractionof bensylic hydrogenatoms Qyatomic bromine (fromCbroam succiniaide)~ndtgrthetrichloroathyl~dical, fmmbenzyl s&b1 ether (I,B-H)andbemaldehyde dimsthylacetal (I,R-0%) has recently teen shown1 to proceed by the follwzlng nmchanism:-Ph.CHR.(Olb) + Br\* (or4C13) + Ph.k(OMs)
EPR and ENDOR spectra were recorded for 2-methyl-9,lO-anthraquinone (tmethylAQ), 2-ethylAQ, 2-tert-butylAQ and 2,fdimethylAQ anion radicals in the solution phase. The EPR spectra were simulated with the help of ENDOR data. The experimental isotropic hyperfine coupling constants (IHFCs) were compared