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Relative reactivities of α-substituted benzyl methyl ethers towards atomic bromine and the trichloromethyl radical

✍ Scribed by R.L. Huang; Kheng H. Lee


Book ID
104223239
Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
157 KB
Volume
6
Category
Article
ISSN
0040-4039

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✦ Synopsis


Abstractionof bensylic hydrogenatoms Qyatomic bromine (fromCbroam succiniaide)~ndtgrthetrichloroathyl~dical, fmmbenzyl s&b1 ether (I,B-H)andbemaldehyde dimsthylacetal (I,R-0%) has recently teen shown1 to proceed by the follwzlng nmchanism:-Ph.CHR.(Olb) + Br* (or4C13) + Ph.k(OMs)