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The reactivity of orgoanophosphorus cobalt hydride-complexes with carbon dioxide

โœ Scribed by V.D. Bianco; S. Doronzo; N. Gallo


Publisher
Elsevier Science
Year
1981
Weight
171 KB
Volume
17
Category
Article
ISSN
0020-1650

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Benzyl chloride and butyl halide each react with CO, catalyzed by 5,10,15,20-tetraphenylporphyrin cobalt (CoTPP) to form phenylacetic acid (in the form of benzyl phenylacetate, the product of electrocarboxylation) or oxalic acid (the direct reduction product of CO,, in the form of dibutyl oxalate),