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The Profound Influence of a Single Metal-Carbon Bond on the Reactivity of Bio-Relevant Cobalt(III) Complexes

✍ Scribed by Mohamed S. A. Hamza; Rudi van Eldik


Publisher
John Wiley and Sons
Year
2004
Weight
58 KB
Volume
35
Category
Article
ISSN
0931-7597

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Reactions of Strained CC Single Bonds wi
✍ Priv.-Doz. Dr. Rudolf Aumann 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB 👁 2 views

C,,H9N and SnBr, respectively. Ion m/e 179 shifts to m/e 182 in the spectrum of the trideuterated compound ( l a ) , while no shift is observed for m/e 199. Both ions are absent in low energy (12 eV) scans. Ion m/e 199 is formed from the molecular ion by ejection of the metal-ligands followed by ex