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The reactivity of ketyl and alkyl radicals in reactions with carbonyl compounds

✍ Scribed by E. T. Denisov

Publisher: Springer
Year: 1998
Tongue: English
Weight: 520 KB
Volume: 47
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf02494263

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## Abstract In the reactions of alkyl‐substituted‐benzenecarboxylic and ‐2‐hydroxybenzenecarboxylic acids (ArCOOH) with alkyl‐substituted phenyl Grignard reagents (RMgX) in the presence of nickel, ketyl radicals ArCO^−^R are formed. The __para__ substituents (H, Me, Et, Isopr and __t__‐Bu) of R i