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The Reactivity of 3-bromo-2-trimethylsilyl-1-propene towards electrophiles A short synthesis of 2-substituted-4-trimethylsilylfurans

โœ Scribed by P. KnocKel; J.F. Normant


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
213 KB
Volume
25
Category
Article
ISSN
0040-4039

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The tetrahydropyranyl ether of (E)-3-bro
โœ R.Bryan Miller; Mohammed I. Al-Hassan ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 224 KB

The tetrahydropyranyl ether of (E)-3-bromo-3-trimethylsilyl-2-propen-l-01 can serve as a single synthon for both the (E)-B-formylvinyl anion and cation depending upon the manner in which the bromine group is stereospecifically replaced by an alkyl group. mmol, 80% yield) of colorless product. GLC a