The Reactivities of 2- And 4-Chloroquinolines with Methoxide, Arylsulfide and Phenoxide ions in Methanol
โ Scribed by Gabriello Illuminati; Gianlorenzo Marino
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- French
- Weight
- 220 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The carcinogens 4-aminobiphenyl, 2-aminofluorene and their N-acetyl derivatives form DNA adducts in vivo with the aryl nitrogen attached at C-8 of guanine. These adducts are proposed to arise through the reaction with the DNA base of a nitrenium ion obtained by N-0 heterolysis of a hydroxylamine est
The kinetics of the reaction of 2-chloro-3-nitropyridine (ortho-like) and 2-chloro-5-nitropyridine (para-like) with a series of aryloxide ions were studied in methanol at different temperatures. Plots of DH โ versus DS โ for both reactions gave good straight lines with isokinetic temperatures of 168