## Abstract The rate of the acid‐catalysed hydrosis of 7‐__syn__‐diazoacetyl‐2‐norbornene (**1a**) is enhanced relative to that of the saturated analogue **5a** by a factor of 835. In contrast to the behaviour of other primary diazoketones, the substitution step is no longer rate‐determining (mecha
The reactions of 7-syn-benzenesulfonamido and 7-syn-carbomethoxyamino-2-exo-bromonorbornane with sodium methoxide in methanol
✍ Scribed by L.H. Zalkow; R.M. Calhoun
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 186 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Performic acid oxidation of exo-2-syn-7-bicyclo[2.2.1]hept-5-enediol (norborn-5-enediol) gives exo-3-exo-5-syn-7tricyclo[2.2.1.02'6]heptanetriol-(nortricyclenetriol), exo-2-endo-3-endo-5-syn-7-, exo-2-endo-3-endo5-anti-7-and exo-2endo-3-exo-5-anti-7-bicyclo[2.2.1]heptanetetrols (norbornanetetrols) a
## Abstract Syntheses of the alcohols **10** and **18**, and the corresponding ketones **11** and **19** are presented. __Endo__‐5, __exo__‐6‐bis (chloromethyl)‐__endo__‐3‐chloro‐__exo__‐2‐norbornanol (**16**) and __endo__‐5‐(bromomethyl)‐__exo__‐6‐(chloromethyl)‐__endo__‐3‐chloro‐__exo__‐2‐norborn