✦ LIBER ✦

The reactions of ozone with propane and ethane

✍ Scribed by R.J. Morrissey; C.C.S.J. Schubert

Publisher: Elsevier Science
Year: 1963
Tongue: English
Weight: 601 KB
Volume: 7
Category: Article
ISSN: 0010-2180
DOI: 10.1016/0010-2180(63)90191-3

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✦ Synopsis

The reactions of ozone with propane and ethane were studied in the temperature range 0" to 60°C in thermostated infra-red gas cells. The major products of the ozone-propane reaction were found to be carbon dioxide, water vapour, acetone, formic acid and methanol. Major products of the ozone-ethane reaction included all the above with the exception of acetone. In the bresence of added oxvtren the activation enerEv for the ozone-brobane reaction, calculated ok the basis of the ix>ression -d [03]/dt=g[&] [C~HB] was'fozhzd to be 14.6 kcal mole-l. The fire-exponential term was 2.12X lOa 1. mole-l set-1. the numbed of moles of ozone conszlmed. The low values obtained for the activation energy are taken to indicate that the initiating agent in the reactions is the ozone molecule.

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