The reactions of olefins with permanganate, ruthenium tetroxide, and osmium tetroxide; dependence of rate on degree of substitution
β Scribed by K.Barry Sharpless; Donald R. Williams
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 120 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In spite of the extensive use of the tetraoxotransition metal reagents (Mn04-,
π SIMILAR VOLUMES
Konishevskaya et al. [I] observed that phosphate ions increased the rate of the reaction between hydrazine and vanadate ions catalyzed by osmium tetroxide. They claimed that phosphate ions form a 1:l complex with osmium tetroxide, & = 250 + 60. We were concerned with this report because of our inter
## Abstract For Abstract see ChemInform Abstract in Full Text.
The evolution of the u C-C1 bands of the infrared spectrum of a Bernoullian though slightly isotactic poly(viny1 chloride) (PVC), with both the degree of s N 2 substitution reaction with sodium benzenethiolate, as studied earlier, and the increase of the nucleophile infrared bands, has been studied