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The reactions of O(1D) with ozone and nitrous oxide

✍ Scribed by Charles S. Goldman; Raymond I. Greenberg; Julian Heicklen

Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
334 KB
Volume
3
Category
Article
ISSN
0538-8066

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✦ Synopsis

Ozoone was photolyzed at room temperature in the presence of N2O at 2537 A and 2288 A to produce O(lD) atoms. These atoms can react with either 0 3 or N20 via ( )

From the quantum yield of Nz, the relative rate constants kga/k6 and kz/kc could be obtained, where k6 = k b a + k6b. The foomer rate constant ratio was found to be 0.37 f 0.03 at 2537 A and 0.33 f 0.03 at 2288 A, in good agreementowith an earlier repprt from our laboratory.

The difference in the two numbers, if real, may reflect differences in reactivity due to different amounts of excess translational energy in the O ( ' 0 ) atom at the two wavelengths.

The ratio kz/ke was found to be 2.6 at 2537 A, but 4.1 at 2288 A.

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