Several cyclic and acyclic enones and their ethylene ketals/acetals were reacted with dimethyl diazomalonate under bis(acetylacetonato)copper(II) catalysis. Cyclohex-2-en-I-one (1) yielded only C-H insertion products 2 and 3, whereas but-3-en-2-one gave a cyclopropane albeit in very low yield. The e
β¦ LIBER β¦
The reactions of ethyl diazoacetate with bis(ethyl acetoacetato)-copper (II) and bis(acetylacetonato)copper (II)
β Scribed by Tadashi Sato
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 135 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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