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The reactions of aromatic Schiff bases with dimethyl acetylenedicarboxylate. II. Reaction in the presence of water

✍ Scribed by Taylor, WC; Vadasz, A


Book ID
125476331
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1982
Tongue
English
Weight
172 KB
Volume
35
Category
Article
ISSN
0004-9425

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The heterocyclic nitrogen ylids react as 1.3 dipoles with acetylenic dipolarophilea, leading, via a hypothetic&L dibydroaromatio cycloadduot, to axowatic bicyclic derivatives, as follows (1,2>: On the other hand, in the case of heterocyclic dioyenomethylids (R P B' = CR), the intenuediary cycloaddu