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The reaction pathway from Speier's to Karstedt's hydrosilylation catalyst

✍ Scribed by Michael F. Lappert; Fiona P.A. Scott


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
166 KB
Volume
492
Category
Article
ISSN
0022-328X

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## Abstract A new catalytic system based on rhodium black using Crabtree's catalyst as an additive for direct hydrogen isotope exchange in aromatic compounds has been investigated. The level of deuterium incorporation can be improved from for example 16 to 93%. The new catalyst mixture tolerates a