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Nitroalkenes as precursors to the aromatic spiroketal skeleton of γ-rubromycin. A Nef-type reaction mediated by Pearlman's catalyst

✍ Scribed by Tanya Capecchi; Charles B de Koning; Joseph P Michael

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 236 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01046-6

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✦ Synopsis

The first synthesis of the benzarmelated spiroketal core of ?-rubromycin using Henry condensations and a novel Nef-type reaction induced by Pearlman's catalyst is described.

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