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The reaction ofo-hydroxybenzyl alcohol with phenyl isocyanate in polar solvents

โœ Scribed by Yong De Han; Peng Fei Yang; Jun Ying Li; Cong De Qiao; Tian Duo Li

Book ID
106513146
Publisher
Springer-Verlag
Year
2010
Tongue
English
Weight
199 KB
Volume
101
Category
Article
ISSN
1878-5190

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๐Ÿ“œ SIMILAR VOLUMES

Effect of polar aprotic solvents and org
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DMF and DMSO catalyse the reaction of butanol with PhNCO but inhibit that with aliphatic isocyanates, due to formation of an active 1 : 1 charge transfer complex with the aromatic isocyanate. Similarity was found in the mode of catalysis of the urethane reaction with these solvents to that with tert

Selectivity of monomeric metaphosphate r
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Evidence is presented for selectivity in the reaction of metaphosphate, W I -, with methanol in preference to t-butanol in acetonitrile solution. In dichloromethane so ution there is also evidence for preferential nucleophilic solvation of reactant by methanol vs. t-butanol. - Following the direct