The reaction of β-stannyl carbonyl compounds with Lewis acids
✍ Scribed by Tadashi Sato; Masami Watanabe; Eigoro Murayama
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 362 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Phenylthioalkyltitanium reagent prepared by the hydrotitanation of alkenyl sulfide using triethylsilane and titanium tetrachloride is found to react with aromatic aldehyde ord,&unsaturated ketone to give the corresponding r-hydroxyalkyl sulfide or b-phenylthio ketone, respectively.
## Abstract With the aid of the molecular refraction and the infrared absorption, the structure of the condensation products of 3‐aminopropanol with 14 carbonyl compounds has been investigated. In some cases, tetrahydro‐1,3‐oxazines, in some Schiff bases, and in some, mixtures of these two possible