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Reaction of β-phenylthioalkyltitanium reagents with carbonyl compounds

✍ Scribed by Takeshi Takeda; Toshio Tsuchida; Ichiro Nakagawa; Shinji Ogawa; Tooru Fujiwara

Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
180 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis

Phenylthioalkyltitanium reagent prepared by the hydrotitanation of alkenyl sulfide using triethylsilane and titanium tetrachloride is found to react with aromatic aldehyde ord,&unsaturated ketone to give the corresponding r-hydroxyalkyl sulfide or b-phenylthio ketone, respectively.

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