𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The reaction of α,β-unsaturated ketoximes into isoxazoles with palladium complexes

✍ Scribed by Kazuyuki Maeda; Takahiro Hosokawa; Shun-Ichi Murahashi; Ichiro Moritani

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
91 KB
Volume
14
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Recently, we described the cyclization reaction of allylphenols with dichlorobis(benzonitrile)palladium to give Z-substituted benzofurans.'

📜 SIMILAR VOLUMES

The mild deoxymation reaction of ketoxim
The mild deoxymation reaction of ketoximes with the dioxygen complex of palladium
✍ Kazuyuki Maeda; Ichiro Moritani; Takahiro Hosokawa; Shun-Ichi Murahashi 📂 Article 📅 1974 🏛 Elsevier Science 🌐 French ⚖ 109 KB

Considerable information concerning to structural studies and inorganic reactions of dioxygen complex of palladium has been considerably accumulated;' however, reactions utilizing these complexes for general organic synthesis are sparse.2

Palladium-catalyzed regioselective react
Palladium-catalyzed regioselective reactions of α-acetoxy-β,γ-unsaturated nitriles and γ-acetoxy-α,β-unsaturated ester with nucleophiles
✍ Jiro Tsuji; Hiroaki Ueno; Yuichi Kobayashi; Hiroshi Okumoto 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 120 KB

e-Acetoxy-8,y-unsaturated nitriles react at room temperature with malonates and acetoacetates in the presence of palladium-phosphine complexes as a catalyst to give y-substituted a,8-unsaturated nitriles selectively. Also yacetoxy-a,8-unsaturated ester was attacked at y-position by malonate.