The reaction of α,β-epoxy sulfoxides with lithium dimethylcuprate giving enolates: A novel synthesis of aldols
✍ Scribed by Tsuyoshi Satoh; Atsushi Sugimoto; Masayuki Itoh; Koji Yamakawa
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 221 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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The Organoselenium-Mediated Reduction of α,β-Epoxy Ketones, α,β-Epoxy Esters, and Their Congeners to β-Hydroxy Carbonyl Compounds: Novel Methodologies for the Synthesis of Aldols and Their Analogues. -The reduction of the title compounds with Na[PhSeB(OEt) 3 ] (prepared by reduction of (PhSe) 2 wi
Exo-trigonal-type intramolecular ring closure of the cf,8-epoxy sulfoxides with hvdroxvl group cave 2-acvl cyclic ethers (5. 6. and 13 membered rings) in good-yields.- In contrast to this, endo-trigonalltype ring closure of the a,8-epoxy sulfoxides was rather difficult. Recently, cyclic ethers hav