Ironcarbonyl Complexes of 5,6-Dimethylid
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Edia Bonfantini; Jean-Luc MΓ©tral; Pierre Vogel
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Article
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1987
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John Wiley and Sons
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German
β 578 KB
The I-dimethoxymethyl-5,6-dimethylidene-7-oxabicyclo[2.2. I jhept-2-ene (9) has been prepared. On treatment with Fe,(CO),, the endocyclic double bond C(2)=C(3) was coordinated first giving the Corresponding exo-Fe(C0)4 complex 10. The latter reacted with Fe,(CO), and afforded cis-heptacarbonyl-p -[(