Reactions of Coordinated cyclic polyolefins. The synthesis and cycloaddition reactions of tricarbonyl[(1,2,3,4-η)-3,7,7-trimethylcycloheptatriene]iron
✍ Scribed by Zeev Goldschmidt; Shlomo Antebi
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 450 KB
- Volume
- 259
- Category
- Article
- ISSN
- 0022-328X
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## Abstract An (__E__)/(__Z)__ mixture (3 : 2) of 7‐benzylidenecycloocta‐1,3,5‐triene (**5**) is obtained when 1‐benzylcycloocta‐1,3,5,7‐tetraene (**7**), prepared by an improved procedure, is treated with __t__‐BuOK in THF. Alternatively, a __ca.__ 9 : 1 mixture (__E__)/(__Z__)‐**5** can be prepar