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The Reaction of Trialkylboranes with Dimethyloxosulfonium Methylide

โœ Scribed by Tufariello, J. J.; Lee, L. T. C.

Book ID
126053786
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
402 KB
Volume
88
Category
Article
ISSN
0002-7863

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An anomalous reaction of dimethyloxosulf
An anomalous reaction of dimethyloxosulfonium methylide
โœ Alexander G. Yurchenko; Natalie N. Melnik; Igor R. Likhotvorik ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 133 KB

On treatment with dimethyloxosulfonium methylide in the presence of sodium methylsulfinylmethide, 3-methylenebicyclo[3.3. I] B? nane-7-one oxide undergoes an unusual transformation to 4,5-dimethylenetricyclo[4.3.1.0 9 ldecane-l-01. Diiethyloxosulfonium methyli& is an extremely important reagent for