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Selective N-methylations of heterocycles with dimethyloxosulfonium methylide

โœ Scribed by Witkop, Bernhard.; Kunieda, Takehisa.


Book ID
111677838
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
295 KB
Volume
35
Category
Article
ISSN
0022-3263

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An anomalous reaction of dimethyloxosulf
โœ Alexander G. Yurchenko; Natalie N. Melnik; Igor R. Likhotvorik ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 133 KB

On treatment with dimethyloxosulfonium methylide in the presence of sodium methylsulfinylmethide, 3-methylenebicyclo[3.3. I] B? nane-7-one oxide undergoes an unusual transformation to 4,5-dimethylenetricyclo[4.3.1.0 9 ldecane-l-01. Diiethyloxosulfonium methyli& is an extremely important reagent for