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The reaction of thionitrites with barton esters: a convenient free radical chain reaction for decarboxylative nitrosation

✍ Scribed by Pierre Girard; Nadine Guillot; William B. Motherwell; Robyn S. Hay-Motherwell; Pierre Potier

Book ID: 104209079
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 741 KB
Volume: 55
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(98)01164-8

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✦ Synopsis

Tertiary thionitdte esters react with primary and secondary O-acyl derivatives of N-hydroxy-2thiopyridone to give trans nitroso dimers as the principal products of a free radical chain reaction.

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