𝔖 Bobbio Scriptorium
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The reaction of thiolsulfinates with trifluoroacetic anhydride: A convenient preparation of β-trifluoro- and β-trichloroacetoxysulfides.

✍ Scribed by Naomichi Furukawa; Tsuyoshi Morishita; Takeshi Akasaka; Shigeru Oae


Book ID
108384881
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
354 KB
Volume
20
Category
Article
ISSN
0040-4039

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The reaction of lithium ester enolates w
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Lithium ester enolates, prepared by the reaction of lithium N-isopropylcyclohexylamide (LIICA) with esters at -78' (eq. 1); react with acid chlorides at this same low temperature to provide satisfactory yields of the corresponding S-keto esters (eq. II). This procedure represents an exceedingly vers