The reaction of sulphur and sulphur compounds with olefinic substances—XIII : The mechanism of interaction of sulphur with (+)-limonene
✍ Scribed by C.G. Moore; M. Porter
- Publisher
- Elsevier Science
- Year
- 1959
- Tongue
- French
- Weight
- 52 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Ethylene ketals of the type (I) cyclise in presence of phosphorus pentoxide in pyrid& to give the ketal (II) which on hydrolysis yields l-phenyl-6:7-dimethoxy4oxo-3:4-dihydroisquinob (III). 1-(4-oxo-cyclohexyl)-6:7-dimethoxy-3:4-dihydroisoquinoline (Vlll) and 2-oxo-3-methyl-g:1& dimethoxy-I 2:3:4:6:7-hexahydro-1 lbH-benzo[a]-quinolizine (XV) were also synthesised.
📜 SIMILAR VOLUMES
## Abstract Data presented for a range of vulcanized rubbers prepared under different conditions show that while olefinic unsaturation becomes reduced by vulcanization in the proportion of one double bond for each sulphur atom combined with a C~5~H‐unit, the original H/C ratio of 8/5 is not altered
SULPHIDE FORMATION IN THE REACTION OF SULPHUR WITH POLYISOPRENES PART vr. FACTORS INFLUENCING CYCLIC ## By GEORGE F. BLOOMNELD Cyclic sulphidcs arc to a large extent secondary products of the reamon of primarily-formcd intermolecular polysulphides with polyisoprene hydrocarbon, and undue prolong