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THE REACTION OF SODIUM PHENOXIDE WITH ALPHACHLOROHYDRACRYLIC ACID

✍ Scribed by Koelsch, C. Frederick


Book ID
126102272
Publisher
American Chemical Society
Year
1930
Tongue
English
Weight
200 KB
Volume
52
Category
Article
ISSN
0002-7863

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Oxiranylidene intermediate in the reacti
✍ Harlan L. Goering; Steven D. Paisley πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 226 KB

The reaction of trans-2-chloro-3-(t-butyl)oxirane with sodium phenoxide in acetonitrile to give trans-2-phenoxy-3-(t-butyl)oxirane involves a-elimination to give an oxiranylidene which undergoes a stereoselective stepwise addition of phenol to give product. ## Recently it was shown that reaction of