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The reaction of secondary phosphines and di-1-adamantylphosphine oxide with trifluoroacetic anhydride and hexafluoroacetone

โœ Scribed by Jens R. Goerlich; Volker Plack; Reinhard Schmutzler


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
642 KB
Volume
76
Category
Article
ISSN
0022-1139

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## Abstract On treatment of a 2,5โ€bissilylsubstituted thiophene Sโ€oxide or dibenzothiophene Sโ€oxide with trifluoroacetic anhydride, the equillibria between the corresponding substrates and hypervalent sulfur compounds (sulfurane or ฮป^4^โ€sulfane) have now been first detected by low temperature NMR e