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Implication of small hydrogen-deuterium kinetic isotope effect in the reaction of quinaldine and 1-methylisoquinoline N-oxides with acetic anhydride

โœ Scribed by S. Tamagaki; S. Kozuka; S. Oae


Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
157 KB
Volume
9
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


The gerreral scheme of the reaction between ~-or ~'-alky!ated pyridine and quinaldSme l,~ox~des with acetic anhydride can be depicted as sho~m belo~z (2),


๐Ÿ“œ SIMILAR VOLUMES


ฮฒ-deuterium kinetic isotope effects in t
โœ Kwang-Ting Liu; Yuh Wern Wu ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 251 KB

A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue