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The reaction of perfluoroalkanesulfinates. IX. Perfluoroalkylation of pyridine and its derivatives with sodium perfluoroalkanesulfinates

โœ Scribed by Wei-Yuan Huang; Jin-Tao Liu; Juan Li


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
294 KB
Volume
71
Category
Article
ISSN
0022-1139

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The rate constants for the reactions of 4-halomethyl-3-nitrobenzoic acids, the nonnitro derivatives, and their ethyl esters with arylthiolates were measured at different temperatures. It was found that the retardation in rate constants compared to benzyl halides is due to the electrostatic repulsion