Reinvestigation of the Reaction of 8-Bromoguanine Derivatives with Sodium Thiosulfate.
β Scribed by Martins Ikaunieks; Marina Madre
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The rate constants for the reactions of 4-halomethyl-3-nitrobenzoic acids, the nonnitro derivatives, and their ethyl esters with arylthiolates were measured at different temperatures. It was found that the retardation in rate constants compared to benzyl halides is due to the electrostatic repulsion
Treatment of the title compound 1 with sodium methoxide X-ray analysis. The structure 2 proposed earlier has to be corrected in favour of 3. in ether in the presence of methanol leads to the bicyclopentyl derivative 3. The structure of 3 was established by