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The reaction of perfluoroalkanesulfinate: A novel method for the preparation of perfluorocarboxylic acid and the coupling product perfluoroalkane

✍ Scribed by Huang Wei-Yuan; Hu Li-Qing

Book ID
112058800
Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
122 KB
Volume
7
Category
Article
ISSN
0256-7660

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Reaction of non-activated olefines with active methylene compounds was accomplished under solid-liquid phase-transfer conditions, in the presence of iodine, to give electrophilic cyclopropanes of a wide range of substituents. Several data to the mechanism of the reaction are also given.