Reaction of non-activated olefins with CH-acids; a novel method for the preparation of electrophilic cyclopropanes

✍ Scribed by László Tóke; Gábor T Szabó; Zoltán Hell; Gábor Tóth

• Book ID: 104221847
• Publisher: Elsevier Science
• Year: 1990
• Tongue: French
• Weight: 217 KB
• Volume: 31
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)88529-9

✦ Synopsis

Reaction of non-activated olefines with active methylene compounds was accomplished under solid-liquid phase-transfer conditions, in the presence of iodine, to give electrophilic cyclopropanes of a wide range of substituents.

Several data to the mechanism of the reaction are also given.