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The reaction of ozone with highly strained bicyclo[n.1.0] alkanes

✍ Scribed by Thomas Preuß; Ehrhardt Proksch; Armin de Meijere

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
210 KB
Volume
19
Category
Article
ISSN
0040-4039

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Cycloadditions of methylenecyclopropanes
Cycloadditions of methylenecyclopropanes and strained bicyclo[n.1.0]alkanes to radicophilic olefins
✍ Armin De Meijere; Horst Wenck; Fereydoun Seyed-Mahdavi; Heinz Günter Viehe; Vinc 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 486 KB

The methylenecyclopropanes 1, 2, 11 upon reaction with a\-donorsubstituted acrylonitriles 3a, 3c gave two types of products, regular [2+21 cycloadducts 6,. 8, 10, 13, 14 and thiacyclopentane derivatives 7, 9. 'Me capto-dative substituted methylenecyclopropane 12 preferentially homodimerized to 15 ev