Ihe reactions of CC1302 with NO and NO2 have been studied by steady-state photolqsis of Clz-HCCl,-Oz-&-NO --NOz mixtures at =I atm: CCl30, + NO -Ccl,0 + NO, (3), CCt,O, + NO2 (t hl) \* CCl,02NOt (+ hi) (4. A); k&k3 = 0.68, independent of temperature-The thermal decomposition of CC1302N02 via the bac
The reaction of O(3P) with CCl2CH2
β Scribed by Eugenio Sanhueza; Julian Heicklen
- Publisher
- Elsevier Science
- Year
- 1975
- Weight
- 947 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0047-2670
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π SIMILAR VOLUMES
Mixtures of Cl:!, CH4, and 0 2 were flash photolyzed a t room temperature and pressures of -60-760 Torr to produce CH3O2. The CH3O2 radicals decay by the second-order process (6) 2CH302products with k g = (3.7 f 0.3) X cm3/sec in good agreement with other studies. This value ignores any removal by s
The reactions of CCl, with O(,P) and O2 and those of CC1302 with NO have been studied at 295 K using discharge flow methods with helium as the bath gas. The rate coefficient for the reaction of CCI, with 0 was found to be (4.2 2 0.6) x lo-'' cm3/s and that for CCI3O2 with NO was (18.6 2 2.8) x lo-''
Collisional deactivation of by the title compounds was investigated through 2 I( P ) 1/2 the use of the time-resolved atomic absorption of excited iodine atoms at Rate 206.2 nm. constants for atomic spin-orbit relaxation by CH 3 Cl, CH 2 Cl 2 , CHCl 3 , CCl 3 F, and CCl 4 are and Οͺ13 Οͺ13 Οͺ14 Οͺ15 3.
The rate constant for the reaction CH302 + NO2 -(products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and a t total pressures between 53 and 580 Torr, k:, = (9.2 f 0.4) X lo8 liter/mole sec so that the rate of formation of the probable primary produc