The Reaction of n - and i -C 4 H 5 Radicals with Acetylene †
✍ Scribed by Senosiain, Juan P.; Miller, James A.
- Book ID
- 126795016
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 272 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
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Reactions of the hydroxyl radical, OH, with several reactants have been studied near 1200 K in shock tube experiments in which UV absorption was used to monitor the OH concentration. The values of the rate coefficients were found to be 2.7 x lo", 2.6 X lo", 2.8 x and 1.26 x 1013 cm3/mol-s for the re
CzH50NO was photolyzed with 366 nm radiation at -48, -22, -2.5, 23, 55, 88, and 120°C in a static system in the presence of NO, 0,, and N,. The quantum yield of CH3CH0, (D{CH3CHO), was measured as a function of reaction conditions. The primary photochemical act is (la) CZHSONO + hv -\* CzH50 + NO an