Primary and q econdery alkyl isocyanides and phenyl isocyanide react with bydrogwn chloride to compounds the structure cf which waa proved, several years ago, to be Ia-b (1). This reaction is the only hewn example of oligomerization of isocyanides by acid species where C-N-addition haa been proved;
The reaction of N-Acyl imines with t-Butyl isocyanide
β Scribed by J. A. Deyrup; K. K. Killion
- Book ID
- 112122770
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1972
- Tongue
- English
- Weight
- 318 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0022-152X
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π SIMILAR VOLUMES
The reaction of N-arylimines of hexaΒ―uoroacetone and CF 3 Si(CH 3 ) 3 (1) in the presence of CsF results in a 48Β±84% yield formation of ArN(H)C(CF 3 ) 3 . The reaction requires an equimolar amount of CsF and rapidly proceeds in solvents such as THF or monoglyme. Interaction of CF 3 NC(CF 3 ) 2 with
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