The rate constants for the reactions C1 + CH,OD + CH,OD + HCI (1) and CH,OH + 0, -HO, + H2C0 (2) have been determined in a discharge flow system near 1 torr pressure with detection of radical and molecular species using collision-free sampling mass spectrometry. The rate constant k l , determined fr
The reaction of methanol with atomic oxygen
โ Scribed by V. Ya. Basevich; S. M. Kogarko; G. A. Furman
- Book ID
- 112438123
- Publisher
- Springer
- Year
- 1975
- Tongue
- English
- Weight
- 433 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1573-9171
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T h e rate constant for the reaction of ground-state oxygen atoms with methanol has been determined between 297 and 544 K by a phase-shift technique using mercury photosensitized decomposition of N20 to generate oxygen atoms. T h e relative oxygen atom concentration was monitored by the chemilumines
The reaction of 1,3-cyclopentadiene (CPD) with ground-state atomic oxygen O ( 3 P ) , produced by mercury photosensitized decomposition of nitrous oxide, was studied. The identified products were carbon monoxide and the following C4H6 isomers: 3-methylcyclopropene, 1,3-butadiene, 1,2-butadiene, and
## Abstract The reaction of hydrogen atoms with diazomethane was used as a source of methyl radicals to study the reaction of oxygen atoms with methyl radicals. This investigation verifies directly the earlier results that formaldehyde is a major product and that the rate constant is greater than 3