## Abstract Patchoulol **(1)** forms 2,2,6,8‐tetramethylbicyclo [5.3.1]undec‐7‐en‐3‐one **(5)** with lead tetraacetate. This ketone undergoes acid‐catalyzed cyclization to 2,6,6,10‐tetramethyltricyclo [5.3.1.0^1,5^]undec‐9‐en‐5‐ol **(10)**, and is reduced to 2 stereoisomeric alcohols with lithium a
The reaction of lead tetraacetate with hydrocarbons
✍ Scribed by Melvyn W. Mosher; Jeffery L. Cox
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 209 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The free radical reaction of lead tetraacetate with hydrocarbons has been investigated. the acetate esters.
📜 SIMILAR VOLUMES
Es konnte noch 1 pg Hg neben 150 pg eines Gemisches vieler Kationen mit einer Genauigkeit von f 4% bestimmt werden. Erfassungsgrenze und Fehlerbreite waren weitgehend durch den Neutronenfluss des zur Verfiigung stehenden Kernreaktors des Physikalischen Instituts der Universitat Base1 gegeben.
## Abstract The reaction of norbornene with lead tetraacetate is found to be much more complex than previously reported. In acetic acid and in benzene, the __syn__‐7‐norbornenyl, 3‐nortricyclyl, and __syn__ and __anti__‐7‐acetoxy‐__exo__‐2‐norbornyl acetates were characterized. In methanol, the iso
It is vell kmown that pyrazolines aoted om by lead tetraacetate are converted into 3-acetog-Al-pyrasolines, oyolopropame derivatives or pyrazolea, depending on the