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The reaction of furan derivatives with azo-bis-isobutyronitrile

✍ Scribed by A. Gandini; J. Rieumont


Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
210 KB
Volume
17
Category
Article
ISSN
0040-4039

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✦ Synopsis


The interaction of free radicals with furan has been studied previously, but only with alkaxy (11, bcnzoyl (2) and aromatic radicals (3-5). The addition reactions to give 2,5_dihydrofurans predominate, but in the case of the phenyl radicals (3-5) substitution at C-2 has been reported.

The mechanism of autoinhibition displayed by vinyl monomers containing the furan ring, such as vinyl 2-furoate (6-8), vinyl 2-fury1 acetate (8), vinyl 2-furylpropionate


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