The reaction of five-membered cyclic trithiocarbonates with n-butyllithium
β Scribed by Kouhei Hatanaka; Shigeo Tanimoto; Tatsuo Oida; Masaya Okano
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 135 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
It was found that the reaction of five-membered cyclic trithiocarbonates with n-butyllithium in tetrahydrofuran is applicable to the preparation of unsymmetrical linear trithiocarbonates and further to the interconversion of cis-and *runs-olefins.
Five-nx?r&ered cyclic tii'chiocarbonates have been s& to be in general readily accessible
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The addition of chlorocarbenel to cyclic v anions has become a reaction of synthetic utility in recent years.2-5 Perhaps the best known reaction of this type is Katz's preparation of benzvalene from the addition of chlorocarbene to the cyclopentadienyl anion (L).2 In all of the anions which have bee
An evaluation of a branching vs sequential mechanism for the reaction of benzoic acid with n-butyllithium favors the latter.