Conversion of five-membered cyclic trithiocarbonates to alkyl vinyl trithiocarbonates with lithium diisopropylamide

The reaction of five-membered cyclic tri

The reaction of five-membered cyclic trithiocarbonates with n-butyllithium

✍ Kouhei Hatanaka; Shigeo Tanimoto; Tatsuo Oida; Masaya Okano 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 135 KB

It was found that the reaction of five-membered cyclic trithiocarbonates with n-butyllithium in tetrahydrofuran is applicable to the preparation of unsymmetrical linear trithiocarbonates and further to the interconversion of cis-and \*runs-olefins. Five-nx?r&ered cyclic tii'chiocarbonates have been