The reaction of dichlorocarbene with secondary amines
β Scribed by M. Saunders; R.W. Murray
- Publisher
- Elsevier Science
- Year
- 1959
- Tongue
- French
- Weight
- 109 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
## Γczyk on the occasion of his 60th birthday The reactions of sterically crowded cycloalkanethiones of type 2 with CHCl 3 /NaOH under phase-transfer catalysis (PTC) with benzyl(triethyl)ammonium chloride (TEBA) as catalyst afforded the corresponding gem.dichlorothiiranes of type 3 in good yields
Kinetic studies established that the monomethylation of a primary amine leads to significantly higher reaction rates with glycidyl ethers. The relative rates for approximately 25 amines were determined in an alcohol solvent under pseudo-firstorder conditions (excess epoxy). The rates were referenced